Rational synthesis of a microporous metal–organic framework with PtS topology using a semi-rigid tetrahedral linker
- 25 February 2010
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in CrystEngComm
- Vol. 12 (7), 2008-2010
- https://doi.org/10.1039/b925903a
Abstract
The assembly of a semi-rigid tetrahedral linker tetrakis[4-(carboxyphenyl)oxamethyl]methane acid (H4X) with CuII yields a binodal 4,4-connected coordination framework of distorted PtS topology, which exhibits permanent porosity confirmed by gas adsorption experiments of N2, H2, CO2, and CH4.Keywords
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