A Luminescent Microporous Metal–Organic Framework for the Fast and Reversible Detection of High Explosives
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- 10 March 2009
- journal article
- Published by Wiley in Angewandte Chemie
- Vol. 48 (13), 2334-2338
- https://doi.org/10.1002/anie.200804853
Abstract
Sensors and sensitivity: A highly luminescent microporous metal-organic framework, [Zn(2)(bpdc)(2)(bpee)] (bpdc = 4,4'-biphenyldicarboxylate; bpee = 1,2-bipyridylethene), is capable of very fast and reversible detection of the vapors of the nitroaromatic explosive 2,4-dinitrotoluene and the plastic explosive taggant 2,3-dimethyl-2,3-dinitrobutane, through redox fluorescence quenching with unprecedented sensitivity (see spectra).Keywords
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