Iron nanoparticles in the coupling of alkyl halides with aryl Grignard reagents
- 3 March 2006
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 13,p. 1398-1400
- https://doi.org/10.1039/b601014h
Abstract
Iron nanoparticles, either formed in situ stabilized by 1,6-bis(diphenylphosphino)hexane or polyethylene glycol (PEG), or preformed stabilized by PEG, are excellent catalysts for the cross-coupling of aryl Grignard reagents with primary and secondary alkyl halides bearing β-hydrogens and they also prove effective in a tandem cyclization/cross-coupling reaction.Keywords
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