Iron-Catalyzed Grignard Cross-Coupling with Alkyl Halides Possessing β-Hydrogens
- 13 March 2004
- journal article
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 6 (8), 1297-1299
- https://doi.org/10.1021/ol049779y
Abstract
Tris(acetylacetonato)iron(III) (Fe(acac)(3)) was found to be an efficient catalyst for the cross-coupling reaction between aryl Grignard reagents and alkyl halides possessing beta-hydrogens. The reaction is applicable to secondary alkyl halides as well as primary ones. [reaction: see text]Keywords
This publication has 38 references indexed in Scilit:
- Fe(III)-Catalyzed Cross-Coupling Between Functionalized Arylmagnesium Compounds and Alkenyl HalidesSynlett, 2001
- Highly Stereo- and Chemoselective Iron-Catalyzed Alkenylation of Organomagnesium CompoundsSynthesis, 1998
- Cu-catalyzed alkylation and Fe catalyzed alkenylation of organomanganese reagentsPublished by Walter de Gruyter GmbH ,1996
- Electron spin resonance studies of the reduction of transition metal complexes with Grignard reagents. 1. Dianion radicals of .beta.-diketonatesJournal of the American Chemical Society, 1976
- Mechanistic studies of iron catalysis in the cross coupling of alkenyl halides and Grignard reagentsThe Journal of Organic Chemistry, 1976
- Synthesis of olefins. Cross-coupling of alkenyl halides and Grignard reagents catalyzed by iron complexesThe Journal of Organic Chemistry, 1975
- Electron-transfer mechanisms for organometallic intermediates in catalytic reactionsAccounts of Chemical Research, 1974
- Iron catalysis in the reaction of grignard reagents with alkyl halidesJournal of Organometallic Chemistry, 1971
- Vinylation of Grignard reagents. Catalysis by ironJournal of the American Chemical Society, 1971
- Coupling of Grignard Reagents with Organic HalidesSynthesis, 1971