Synthetic Approach to Polysubstituted Furans: An Efficient Addition/Oxidative Cyclization of Alkynoates and 1,3-Dicarbonyl Compounds
- 7 January 2010
- journal article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 75 (3), 966-968
- https://doi.org/10.1021/jo902375k
Abstract
A novel and reliable method for the direct construction of polysubstituted furans is reported. The key transformation involves Sn(II)- and Cu(I)-involved addition/oxidative cyclization of alkynoates and 1,3-dicarbonyl compounds in the presence of 2,3-dichloro-5,6-dicyanobenzoquinone.Keywords
This publication has 49 references indexed in Scilit:
- Furan Based Cyclic Oligopeptides Selectively Target G-QuadruplexJournal of Medicinal Chemistry, 2007
- Chemical Routes for the Transformation of Biomass into ChemicalsChemical Reviews, 2007
- Synthesis, characterization and photocross-linking of copolymers of furan and aliphatic hydroxyethylesters prepared by transesterificationPolymer, 2005
- Salts of extended tetrathiafulvalene analogues: relationships between molecular structure, electrochemical properties and solid state organisationChemical Society Reviews, 2004
- Synthesis of 3-substituted furylethylaminesChemistry of Heterocyclic Compounds, 1999
- Furans in polymer chemistryProgress in Polymer Science, 1997
- Difuryl polyenes as precursors of highly conducting electrogenerated conjugated polymersJournal of Electroanalytical Chemistry, 1996
- Five-membered heteroaromatic rings as intermediates in organic synthesisChemical Reviews, 1986
- Pseudopterolide, an irregular diterpenoid with unusual cytotoxic properties from the Caribbean sea whip Pseudopterogorgia acerosa (Pallas) (Gorgonacea)Journal of the American Chemical Society, 1982
- Tumor inhibitors. 69. Structure-cytotoxicity relations among the sesquiterpene lactonesJournal of Medicinal Chemistry, 1971