Adsorption properties and structure of CO2 adsorbed on open coordination sites of metal–organic framework Ni2(dhtp) from gas adsorption, IR spectroscopy and X-ray diffraction
- 24 September 2008
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 41,p. 5125-5127
- https://doi.org/10.1039/b810574j
Abstract
The microporous metal–organic framework Ni2(dhtp) (H4dhtp = 2,5-dihydroxyterephthalic acid) shows distinct end-on CO2 coordination to coordinatively unsaturated nickel sites giving rise to high CO2 adsorption capacity at sub-atmospheric pressures and ambient temperatures.Keywords
This publication has 31 references indexed in Scilit:
- On the breathing effect of a metal–organic framework upon CO2 adsorption: Monte Carlo compared to microcalorimetry experimentsChemical Communications, 2007
- Metal−Organic Frameworks with Exceptionally High Capacity for Storage of Carbon Dioxide at Room TemperatureJournal of the American Chemical Society, 2005
- Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47Journal of the American Chemical Society, 2005
- Flexibility in metal-organic framework materials: Impact on sorption propertiesJournal of Solid State Chemistry, 2005
- Flexible microporous coordination polymersJournal of Solid State Chemistry, 2005
- Improved immobilized carbon dioxide capture sorbentsFuel Processing Technology, 2005
- Development of Supported Ethanolamines and Modified Ethanolamines for CO2 CaptureIndustrial & Engineering Chemistry Research, 2005
- Preparation and characterization of novel CO2 “molecular basket” adsorbents based on polymer-modified mesoporous molecular sieve MCM-41Microporous and Mesoporous Materials, 2003
- A Technical, Economic, and Environmental Assessment of Amine-Based CO2 Capture Technology for Power Plant Greenhouse Gas ControlEnvironmental Science & Technology, 2002
- Experimental and Quantum Chemical Studies on the Adsorption of Carbon Dioxide on Alkali-Metal-Exchanged ZSM-5 ZeolitesThe Journal of Physical Chemistry B, 2000