Different Adsorption Behaviors of Methane and Carbon Dioxide in the Isotypic Nanoporous Metal Terephthalates MIL-53 and MIL-47
Top Cited Papers
- 13 September 2005
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 127 (39), 13519-13521
- https://doi.org/10.1021/ja054668v
Abstract
A distinct step in the isotherm occurs during the adsorption of CO2 on MIL-53 at 304 K. Such behavior is neither observed during the adsorption of CH4 on MIL-53 nor during the adsorption on the isostructural MIL-47. This phenomenon seems to be due to a different mechanism than that of previous adsorption steps on MOF samples. It is suggested that a breathing behavior is induced in MIL-53 during CO2 adsorption.Keywords
This publication has 26 references indexed in Scilit:
- Strategies for Hydrogen Storage in Metal–Organic FrameworksAngewandte Chemie-International Edition, 2005
- Crystallized Frameworks with Giant Pores: Are There Limits to the Possible?Accounts of Chemical Research, 2005
- Adsorption of Gases and Vapors on Nanoporous Ni2(4,4‘-Bipyridine)3(NO3)4 Metal−Organic Framework Materials Templated with Methanol and Ethanol: Structural Effects in Adsorption KineticsJournal of the American Chemical Society, 2004
- A Rationale for the Large Breathing of the Porous Aluminum Terephthalate (MIL‐53) Upon HydrationChemistry – A European Journal, 2004
- Reticular synthesis and the design of new materialsNature, 2003
- Very Large Breathing Effect in the First Nanoporous Chromium(III)-Based Solids: MIL-53 or CrIII(OH)·{O2C−C6H4−CO2}·{HO2C−C6H4−CO2H}x·H2OyJournal of the American Chemical Society, 2002
- Dynamic channels of a porous coordination polymer responding to external stimuliPhysical Chemistry Chemical Physics, 2002
- Gravimetric measurement of binary gas adsorption equilibria of methane—carbon dioxide mixtures on activated carbonGas Separation & Purification, 1995
- Adsorption by MFI-type zeolites examined by isothermal microcalorimetry and neutron diffraction. 2. Nitrogen and carbon monoxideLangmuir, 1993
- The adsorption of methane on H-ZSM-5 zeoliteThermochimica Acta, 1984