Unprecedented thermal rearrangement of push–pull-chromophore–[60]fullerene conjugates: formation of chiral 1,2,9,12-tetrakis-adducts
- 17 June 2010
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 46 (29), 5334-5336
- https://doi.org/10.1039/c0cc00881h
Abstract
Push–pull-chromophore–[60]fullerene conjugates featuring N,N-dimethylanilino-substituted 1,1,4,4-buta-1,3-dienes directly attached to the carbon sphere are transformed into chiral 1,2,9,12-tetrakis-adducts by a novel thermal rearrangement pathway.Keywords
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