A Tetranuclear 3d−4f Single Molecule Magnet: [CuIILTbIII(hfac)2]2
Top Cited Papers
- 20 December 2003
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (2), 420-421
- https://doi.org/10.1021/ja037365e
Abstract
We report now the first single molecule magnet (SMM) consisting of d−f elements. The present study demonstrates that the synthesis of the d−f polynuclear molecule is a very promising approach to SMMs. (1) The d−f polynuclear molecule can be easily synthesized by the assembly reaction of the d-component and the f-component, (2) the high-spin ground state can be generated by a smaller number of metal ions than the d complex, and (3) the molecular magnetic anisotropy is easily derived from the f-component.Keywords
This publication has 7 references indexed in Scilit:
- Nature of Copper(II)−Lanthanide(III) Magnetic Interactions and Generation of a Large Magnetic Moment with Magnetic Anisotropy of 3d−4f Cyclic Cylindrical Tetranuclear Complexes [CuIILLnIII(hfac)2]2, (H3L = 1-(2-Hydroxybenzamido)-2-(2-hydroxy-3-methoxybenzylideneamino)ethane and Hhfac = Hexafluoroacetylacetone, LnIII = Eu, Gd, Tb, Dy)Inorganic Chemistry, 2002
- A Cyano-Bridged Single-Molecule Magnet: Slow Magnetic Relaxation in a Trigonal Prismatic MnMo6(CN)18 ClusterJournal of the American Chemical Society, 2002
- Single-Molecule Magnets: A New Family of Mn12 Clusters of Formula [Mn12O8X4(O2CPh)8L6]Journal of the American Chemical Society, 2002
- Macroscopic quantum tunnelling of magnetization in a single crystal of nanomagnetsNature, 1996
- Large Clusters of Metal Ions: The Transition from Molecular to Bulk MagnetsScience, 1994
- Magnetic bistability in a metal-ion clusterNature, 1993
- High-spin molecules: [Mn12O12(O2CR)16(H2O)4]Journal of the American Chemical Society, 1993