Dual Catalysis Strategies in Photochemical Synthesis
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Open Access
- 25 April 2016
- journal article
- review article
- Published by American Chemical Society (ACS) in Chemical Reviews
- Vol. 116 (17), 10035-10074
- https://doi.org/10.1021/acs.chemrev.6b00018
Abstract
The interaction between an electronically excited photocatalyst and an organic molecule can result in the genertion of a diverse array of reactive intermediates that can be manipulated in a variety of ways to result in synthetically useful bond constructions. This Review summarizes dual-catalyst strategies that have been applied to synthetic photochemistry. Mechanistically distinct modes of photocatalysis are discussed, including photoinduced electron transfer, hydrogen atom transfer, and energy transfer. We focus upon the cooperative interactions of photocatalysts with redox mediators, Lewis and Brønsted acids, organocatalysts, enzymes, and transition metal complexes.Funding Information
- Alfred P. Sloan Foundation
- National Institute of General Medical Sciences (GM095666, GM09888)
This publication has 335 references indexed in Scilit:
- Merging Visible-Light Photocatalysis and Transition-Metal Catalysis in the Copper-Catalyzed Trifluoromethylation of Boronic Acids with CF3IJournal of the American Chemical Society, 2012
- Catalytic Asymmetric α-Acylation of Tertiary Amines Mediated by a Dual Catalysis Mode: N-Heterocyclic Carbene and Photoredox CatalysisJournal of the American Chemical Society, 2012
- Photocatalytic [2 + 2] Cycloadditions of Enones with Cleavable Redox AuxiliariesOrganic Letters, 2012
- Functionally Diverse Nucleophilic Trapping of Iminium Intermediates Generated Utilizing Visible LightOrganic Letters, 2011
- Room-Temperature C–H Arylation: Merger of Pd-Catalyzed C–H Functionalization and Visible-Light PhotocatalysisJournal of the American Chemical Society, 2011
- Visible light photocatalysis of radical anion hetero-Diels–Alder cycloadditionsTetrahedron, 2011
- [3+2] Cycloadditions of Aryl Cyclopropyl Ketones by Visible Light PhotocatalysisJournal of the American Chemical Society, 2011
- Enantioselective α-Benzylation of Aldehydes via Photoredox OrganocatalysisJournal of the American Chemical Society, 2010
- Enantioselective α-Trifluoromethylation of Aldehydes via Photoredox OrganocatalysisJournal of the American Chemical Society, 2009
- Crossed Intermolecular [2+2] Cycloadditions of Acyclic Enones via Visible Light PhotocatalysisJournal of the American Chemical Society, 2009