Elemental Sulfur and Molybdenum Disulfide Composites for Li–S Batteries with Long Cycle Life and High-Rate Capability
- 19 May 2016
- journal article
- research article
- Published by American Chemical Society (ACS) in ACS Applied Materials & Interfaces
- Vol. 8 (21), 13437-13448
- https://doi.org/10.1021/acsami.6b03200
Abstract
The practical implementation of Li-S technology has been hindered by short cycle life and poor rate capability owing to deleterious effects resulting from the varied solubility of different Li polysulfide redox products. Here we report the preparation and utilization of composites with a sulfur rich matrix and molybdenum disulfide (MoS2) inclusions as Li-S cathode materials with the capability to mitigate the dissolution of the Li polysulfide redox products via the MoS2 inclusions acting as "polysulfide anchors". The in situ composite formation was completed via a facile, one-pot method with commercially available starting materials. The composites were afforded by first dispersing MoS2 directly in liquid elemental sulfur (S8) with sequential polymerization of the sulfur phase via thermal ring opening polymerization (ROP) or copolymerization via inverse vulcanization. To highlight the practical utility of this system, it was demonstrated that the composite formation methodology was amenable to larger scale processes with composites easily prepared in 100 g batches. Cathodes fabricated with the high sulfur content composites as the active material afforded Li-S cells which exhibited extended cycle lifetimes of up to 1000 cycles with low capacity decay (0.07% per cycle) and demonstrated exceptional rate capability with the delivery of reversible capacity up to 500 mAh/g at 5C.Funding Information
- Division of Chemistry (CHE-1305773)
- University of Arizona
- National Institute of Standards and Technology (70NANB12H164)
- National Research Foundation of Korea (2010-0018290, NRF-2015R1D1A1A01056874, R31-10013)
- Institute for Basic Science (IBS-R006-G1)
- Kuraray Co., Ltd.
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