Highly Efficient Addition of Activated Methylene Compounds to Alkenes Catalyzed by Gold and Silver
- 15 May 2004
- journal article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (22), 6884-6885
- https://doi.org/10.1021/ja0482637
Abstract
A highly efficient intermolecular addition of 1,3-diketones to alkenes catalyzed by AuCl3/AgOTf was developed. A mechanistic rationale for the reaction has been proposed via a α-C−H activation.Keywords
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