Full‐Spectrum Persistent Luminescence Tuning Using All‐Inorganic Perovskite Quantum Dots
- 27 March 2019
- journal article
- research article
- Published by Wiley in Angewandte Chemie-International Edition
- Vol. 58 (21), 6943-6947
- https://doi.org/10.1002/anie.201901045
Abstract
The applications of persistent luminescence phosphors as night or dark‐light vision materials in many technological fields have fuelled up a growing demand for rational control over the emission profiles of the phosphors, which, however, remains a daunting challenge so far. Herein, we report a unique strategy to fine‐tuning the persistent luminescence by using all‐inorganic CsPbX3 (X = Cl, Br, and I) perovskite quantum dots (PeQDs) as efficient light conversion materials. Full‐spectrum persistent luminescence with wavelengths covering the entire visible spectral region is achieved through tailoring of the PeQDs bandgap, in parallel with narrow bandwidth of PeQDs and highly synchronized afterglow decay due to the single energy storage source. These findings break through the limitations of traditional afterglow phosphors, thereby opening up new opportunities for persistent luminescence materials towards many revolutionary applications such as making a white‐emitting persistent light source and dark‐light multicolor displays.Keywords
Funding Information
- CAS-SAFEA International Partnership Program for Creative Research Teams
- National Natural Science Foundation of China (U1805252, 21875250, 51872048, 11774345)
- Youth Innovation Promotion Association of the Chinese Academy of Sciences (2016277)
This publication has 47 references indexed in Scilit:
- Persistent Luminescence in Non-Eu2+-Doped Compounds: A ReviewMaterials, 2013
- Persistent Luminescence in Eu2+-Doped Compounds: A ReviewMaterials, 2010
- Mn[sup 4+]-Activated Red Photoluminescence in K[sub 2]SiF[sub 6] PhosphorJournal of the Electrochemical Society, 2008
- Mechanism of Phosphorescence Appropriate for the Long-Lasting Phosphors Eu2+-Doped SrAl2O4 with Codopants Dy3+ and B3+Chemistry of Materials, 2005
- Mechanism of Persistent Luminescence in Eu[sup 2+] and Dy[sup 3+] Codoped Aluminate and Silicate CompoundsJournal of the Electrochemical Society, 2005
- Systematic behaviour in trivalent lanthanide charge transfer energiesJournal of Physics: Condensed Matter, 2003
- Cathodoluminescence and Photoluminescence of Nanocrystal PhosphorsJournal of the Electrochemical Society, 2002
- Preparation of long-afterglow Sr4Al14O25-based luminescent material and its optical propertiesMaterials Letters, 2001
- A New Long Phosphorescent Phosphor with High Brightness, SrAl2 O 4 : Eu2 + , Dy3 +Journal of the Electrochemical Society, 1996
- Glow Curves with General Order KineticsJournal of the Electrochemical Society, 1969