Persistent Luminescence in Non-Eu2+-Doped Compounds: A Review

Abstract

During the past few decades, the research on persistent luminescent materials has focused mainly on Eu²⁺-doped compounds. However, the yearly number of publications on non-Eu²⁺-based materials has also increased steadily. By now, the number of known persistent phosphors has increased to over 200, of which over 80% are not based on Eu²⁺, but rather, on intrinsic host defects, transition metals (manganese, chromium, copper, etc.) or trivalent rare earths (cerium, terbium, dysprosium, etc.). In this review, we present an overview of these non-Eu²⁺-based persistent luminescent materials and their afterglow properties. We also take a closer look at some remaining challenges, such as the excitability with visible light and the possibility of energy transfer between multiple luminescent centers. Finally, we summarize the necessary elements for a complete description of a persistent luminescent material, in order to allow a more objective comparison of these phosphors.