Homochiral crystallization of helical coordination chains bridged by achiral ligands: can it be controlled by the ligand structure?

Abstract
Homochiral/heterochiral crystallizations of helical chiral polymer chains bridged by achiral poly-pyridyl ligands dependent on the structures of the bridging ligands and independent on the solvent are described, implying a possible strategy to design achiral crystals of helical chains using chiral bridging ligands.

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