Catalytic C−H Amination for the Preparation of Substituted 1,2-Diamines
- 5 August 2008
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 130 (34), 11248-11249
- https://doi.org/10.1021/ja803344v
Abstract
Rhodium-catalyzed C−H insertion of hydroxylamine-derived sulfamate esters makes possible the synthesis of unique oxathiadiazinane heterocycles, which upon mild reduction furnish differentially substituted 1,2-diamine products. This highly chemo- and diastereoselective transformation underscores the power of catalytic C−H functionalization as a general approach to C−N bond construction.Keywords
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