White light emission from transparent SiO2 glass prepared from nanometer-sized silica particles

Abstract
We report that nanometer-sized silicon-dioxide particles are sintered to optical transparency at temperatures even below 1000°C , forming nonporous bulk silica glass. The resultant silica glass exhibits visible emission, which appears white to the naked eye, in the wavelength range from 400to700nm at room temperature under ultraviolet excitation. The observed emission is quite stable after prolonged exposure to the atmosphere and shows no appreciable light-induced degradation. The present photoluminescence characteristics are found to be basically different from those reported previously for silica nanoparticles and silica-based porous materials.