Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions
- 14 February 2013
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 49 (26), 2682-2684
- https://doi.org/10.1039/c3cc39286d
Abstract
The SCSC transformation of a 1D polymer [Cd(1,3-bdc)(4-spy)2]n produced a 2D polymer [Cd(1,3-bdc)(4-spy)(HT-ppcb)0.5]n through the [2+2] photodimerization reaction. Hydrothermal reactions of HT-ppcb with CdCl2, 1,3-H2bdc and H2O2 afforded another 2D polymer {[Cd(H2O)(1,3-bdc)(bpbpf)]·H2O}n in which HT-ppcb underwent in situ oxidation to form a unique furan-based ligand bpbpf.Keywords
This publication has 38 references indexed in Scilit:
- Softening and Hardening of Macro‐ and Nano‐Sized Organic Cocrystals in a Single‐Crystal TransformationAngewandte Chemie, 2011
- X-ray observation of a transient hemiaminal trapped in a porous networkNature, 2009
- Stacking of double bonds for photochemical [2+2] cycloaddition reactions in the solid stateChemical Communications, 2008
- Supramolecular Control of Reactivity in the Solid State: From Templates to Ladderanes to Metal−Organic FrameworksAccounts of Chemical Research, 2008
- Supramolecular structural transformations involving coordination polymers in the solid stateCoordination Chemistry Reviews, 2007
- Metal-mediated reactivity in the organic solid state: from self-assembled complexes to metal–organic frameworksChemical Society Reviews, 2007
- Formation of an Organometallic Ladderane Derivative by Dynamic Topochemical Reaction ControlAngewandte Chemie, 2006
- Reactions Between or Within Molecular CrystalsAngewandte Chemie, 2004
- Functional Porous Coordination PolymersAngewandte Chemie, 2004
- Self-Assembling CapsulesChemical Reviews, 1997