Metal-mediated reactivity in the organic solid state: from self-assembled complexes to metal–organic frameworks
- 8 May 2007
- journal article
- review article
- Published by Royal Society of Chemistry (RSC) in Chemical Society Reviews
- Vol. 36 (8), 1239-1248
- https://doi.org/10.1039/b516074j
Abstract
The purpose of this tutorial review is to address the use of metal ions to mediate reactions in the organic solid state. We describe metal complexes and coordination networks that facilitate dimerizations, oligomerizations and polymerizations of olefins and acetylenes via irradiation (e.g. ultraviolet (UV) and 60Co γ-rays) and thermal annealing. We show how metal ions can be utilized to direct the formation of polymers and molecules. We also describe how supramolecular chemistry has recently influenced dimerization processes in self-assembled metal–organic solids.Keywords
This publication has 54 references indexed in Scilit:
- Synthesis of Organic Photodimeric Cage Molecules Based on Cycloaddition via Metal−Ligand Directed AssemblyJournal of the American Chemical Society, 2007
- A Rational Approach to Crosslinking of Coordination Polymers Using the Photochemical [2+2] Cycloaddition ReactionMacromolecular Rapid Communications, 2006
- Supramolecular isomerism in multivalent metal-templated assemblies with topochemical influence in the regioselective synthesis of tetrakis(2-pyridyl)cyclobutane isomersChemical Communications, 2006
- Solid-state polymerization of bis(but-3-enoato)zinc: the generation of a stereoregular oligomerChemical Communications, 2000
- Solid-State Polymerization of Aquabis(3-butenoato)calciumChemistry of Materials, 1998
- A study on the photochemical dimerization of coumarins in the solid stateThe Journal of Organic Chemistry, 1985
- The Solid-State Polymerization of Hydrated Barium MethacrylateMacromolecules, 1971
- Solid-State Polymerization of Hydrated Calcium AcrylateMacromolecules, 1970
- Polymerization in the crystalline state. II. Alkali acrylates and methacrylatesJournal of Polymer Science, 1962
- Photodimere einiger γ‐Keto‐pentadien‐DerivateBerichte der deutschen chemischen Gesellschaft (A and B Series), 1925