Design and Synthesis of a Low Bandgap Small Molecule Acceptor for Efficient Polymer Solar Cells

Abstract
A novel non-fullerene acceptor, possessing a very low bandgap of 1.34 eV and a high-lying lowest unoccupied molecular orbital level of −3.95 eV, is designed and synthesized by introducing electron-donating alkoxy groups to the backbone of a conjugated small molecule. Impressive power conversion efficiencies of 8.4% and 10.7% are obtained for fabricated single and tandem polymer solar cells.
Funding Information
  • Ministry of Science and Technology of the People's Republic of China (2014CB643501)
  • National Natural Science Foundation of China (21325419, 91333204, 51373181)
  • Chinese Academy of Sciences (XDB12030200, KJZD‐EW‐J01)