Highly Efficient Organic Solar Cells with Improved Vertical Donor–Acceptor Compositional Gradient Via an Inverted Off‐Center Spinning Method

Abstract
A novel, yet simple solution fabrication technique to address the trade‐off between photocurrent and fill factor in thick bulk heterojunction organic solar cells is described. The inverted off‐center spinning technique promotes a vertical gradient of the donor–acceptor phase‐separated morphology, enabling devices with near 100% internal quantum efficiency and a high power conversion efficiency of 10.95%.
Funding Information
  • Office of Naval Research (N000141410531)
  • China Scholarship Council (201308510084)
  • Fundamental Research Funds for the Central Universities (ZYGX2014J046)
  • Open Foundation of State Key Laboratory of Electronic Thin Films and Integrated Devices (KFJJ201410)

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