A Dodecameric Water Cluster Built around a Cyclic Quasiplanar Hexameric Core in an Organic Supramolecular Complex of a Cryptand

Abstract
An infinite network is formed by the hydrogen bonding of a cluster of 12 hydrogen‐bonded water molecules (see picture) to the secondary amino nitrogen atoms of a laterally nonsymmetric azacryptand. This mode of association had not previously been predicted or found experimentally.