Self-assembly of nanoparticles into structured spherical and network aggregates
Top Cited Papers
- 1 April 2000
- journal article
- letter
- Published by Springer Science and Business Media LLC in Nature
- Vol. 404 (6779), 746-748
- https://doi.org/10.1038/35008037
Abstract
Multi-scale ordering of materials is central for the application of molecular systems1,2,3 in macroscopic devices4,5. Self-assembly based on selective control of non-covalent interactions6,7,8 provides a powerful tool for the creation of structured systems at a molecular level, and application of this methodology to macromolecular systems provides a means for extending such structures to macroscopic length scale9,10,11. Monolayer-functionalized nanoparticles can be made with a wide variety of metallic and non-metallic cores, providing a versatile building block for such approaches. Here we present a polymer-mediated ‘bricks and mortar’ strategy for the ordering of nanoparticles into structured assemblies. This methodology allows monolayer-protected gold particles to self-assemble into structured aggregates while thermally controlling their size and morphology. Using 2-nm gold particles as building blocks, we show that spherical aggregates of size 97 ± 17 nm can be produced at 23 °C, and that 0.5–1 µm spherical assemblies with (5–40) × 105 individual subunits form at -20 °C. Intriguingly, extended networks of ∼50-nm subunits are formed at 10 °C, illustrating the potential of our approach for the formation of diverse structural motifs such as wires and rods. These findings demonstrate that the assembly process provides control over the resulting aggregates, while the modularity of the ‘bricks and mortar’ approach allows combinatorial control over the constituents, providing a versatile route to new materials systems.Keywords
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