Chemical Effects on the Lifetime of-Hole States
- 11 September 1972
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review Letters
- Vol. 29 (11), 689-692
- https://doi.org/10.1103/physrevlett.29.689
Abstract
The linewidths of photoelectron energy spectra have been measured for carbon, nitrogen, and oxygen, each in a variety of molecules in the gas phase. The linewidths of a given element increase with decreasing binding energy of the electron. We interpret these changes in linewidth to be due to changes in the lifetime of the hole caused by changes in the chemical environment.
Keywords
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