Aspects of Manganese (III) - Promoted Oxidative Free Radical Cyclizations to Functionalized Bicyclic Systems
- 1 April 1991
- journal article
- research article
- Published by Informa UK Limited in Synthetic Communications
- Vol. 21 (7), 915-922
- https://doi.org/10.1080/00397919108019776
Abstract
The stereospecific formation of trans-decalin 7 from oxidative radical cyclization of 6 and formation of functionalized bicyclic systems from radical cyclization of 3 are detailed.Keywords
This publication has 29 references indexed in Scilit:
- Manganese(III)-based oxidative free-radical cyclization of unsaturated .beta.-keto esters, 1,3-diketones, and malonate diestersThe Journal of Organic Chemistry, 1990
- Manganese(III)-based oxidative free-radical tandem and triple cyclizationsJournal of the American Chemical Society, 1990
- Manganese(III)-based oxidative free-radical cyclizations. Oxidative cyclization and aromatization of 3-oxo-6-heptenoate estersThe Journal of Organic Chemistry, 1989
- Mechanism of manganese(III)-based oxidation of .beta.-keto estersThe Journal of Organic Chemistry, 1988
- Manganese (III) based oxidative free-radical cyclizations. 2. Polycyclization reactions proceeding through tertiary cations.Tetrahedron Letters, 1987
- Manganese(III)-based oxidative free radical cyclizations. 5. Termination of polycyclization by oxidative .beta.-hydride eliminationThe Journal of Organic Chemistry, 1987
- Manganese (III) based oxidative free-radical cyclizations. 3. Polycyclization reactions proceeding through secondary radicals.Tetrahedron Letters, 1987
- Manganese(III)-based oxidative free-radical cyclization. Synthesis of (.+-.)-podocarpic acidThe Journal of Organic Chemistry, 1985
- Oxidation by metal salts. IV. A new method for the preparation of .gamma.-lactones by the reaction of manganic acetate with olefinsJournal of the American Chemical Society, 1968
- Oxidation reactions of manganese(III) acetate. II. Formation of .gamma.-lactones from olefins and acetic acidJournal of the American Chemical Society, 1968