Dynamic Control of Chiral Space in a Catalytic Asymmetric Reaction Using a Molecular Motor
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- 18 March 2011
- journal article
- research article
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 331 (6023), 1429-1432
- https://doi.org/10.1126/science.1199844
Abstract
Photoisomerization of a molecular catalyst changes its conformation and switches the chirality of its reaction product.Keywords
This publication has 18 references indexed in Scilit:
- Solvent‐Dependent Enantiodivergent Mannich‐Type Reaction: Utilizing a Conformationally Flexible Guanidine/Bisthiourea OrganocatalystAngewandte Chemie-International Edition, 2010
- Artificial Light‐Gated Catalyst SystemsAngewandte Chemie-International Edition, 2010
- Photoswitchable Intramolecular H-Stacking of PerylenebisimideJournal of the American Chemical Society, 2010
- Highly Enantioselective Organocatalytic Sulfa-Michael Addition to α,β-Unsaturated KetonesThe Journal of Organic Chemistry, 2010
- Enantioselective Organocatalytic Direct Michael Addition of Nitroalkanes to Nitroalkenes Promoted by a Unique Bifunctional DMAP-ThioureaJournal of the American Chemical Society, 2008
- The advent and development of organocatalysisNature, 2008
- A redesign of light-driven rotary molecular motorsOrganic & Biomolecular Chemistry, 2007
- Nanomotor rotates microscale objectsNature, 2006
- Enantioselective Michael Reaction of Malonates to Nitroolefins Catalyzed by Bifunctional OrganocatalystsJournal of the American Chemical Society, 2003
- Addition of aromatic thiols to conjugated cycloalkenones, catalyzed by chiral .beta.-hydroxy amines. A mechanistic study of homogeneous catalytic asymmetric synthesisJournal of the American Chemical Society, 1981