Effects of processing history on the modulus of silica xerogel films
- 1 December 2001
- journal article
- Published by AIP Publishing in Journal of Applied Physics
- Vol. 90 (11), 5832-5834
- https://doi.org/10.1063/1.1412266
Abstract
Sintered xerogel films (porous SiO2) show a higher elastic modulus than other amorphous low dielectric constant (K) materials available for the same value of K. By comparing xerogels that were sintered, templated or made with ethylene glycol or ethanol as solvents, we show that process history is at least as important as the chemistry of the solid matrix or the porosity. The modulus extrapolated to zero porosity for the porous sintered and templated films is the same as those of the dense films made by chemical vapor deposition of SiO2. This suggests that the solid matrix for sintered xerogel films is close to ideal and their modulus is better because of the ordered arrangement of pores and fusion of particles making up the matrix. The modulus measured by nanoindentation on thick xerogel films (>0.8 μm) is well explained by the open cell foam model.Keywords
This publication has 20 references indexed in Scilit:
- Influence of barrier and cap layer deposition on the properties of capped and non-capped porous silicon oxideMicroelectronic Engineering, 2001
- Mechanical properties of xerogel silica films derived from stress versus temperature and cracking experimentsJournal of Applied Physics, 2000
- Preparation of Highly Porous Silica Aerogel Thin Film by Supercritical DryingJapanese Journal of Applied Physics, 2000
- Low Dielectric Constant Mesoporous Silica Films Through Molecularly Templated SynthesisAdvanced Materials, 2000
- Simultaneous measurement of Young’s modulus, Poisson ratio, and coefficient of thermal expansion of thin films on substratesJournal of Applied Physics, 2000
- Micromechanical properties of silica aerogelsApplied Physics Letters, 1999
- Surface modified spin-on xerogel films as interlayer dielectricsJournal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, 1999
- Different kinds of structure in aerogels: relationships with the mechanical propertiesJournal of Non-Crystalline Solids, 1998
- Silica aerogel films at ambient pressureJournal of Non-Crystalline Solids, 1995
- Mechanical properties of sol-gel coatingsJournal of Non-Crystalline Solids, 1990