A highly oxidized Re27+ species with an electron-poor bond of order 3.5
- 4 March 2003
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- No. 7,p. 1218-1219
- https://doi.org/10.1039/b301360j
Abstract
The first paddlewheel complex with an Re2 7+ core and an electron-poor bond order of 3.5 is paramagnetic and shows a metal–metal bond lengthening of 0.035 Å relative to the corresponding compound having a quadruple bond and an Re2 6+ core.Keywords
This publication has 4 references indexed in Scilit:
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- The First Structurally Confirmed Paddlewheel Compound with an M27+ Core: [Os2(hpp)4Cl2](PF6)Inorganic Chemistry, 2003
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- A very short Re26+ quadruple bond: first DFT calculations on a paddlewheel complex with an element of the third transition seriesJ. Chem. Soc., Dalton Trans., 1999