X-ray structure and magnetochemical study on a Co(II) complex of 2-acetyl-1,3-indandione
- 15 November 2008
- journal article
- research article
- Published by Taylor & Francis Ltd in Journal of Coordination Chemistry
- Vol. 61 (24), 3879-3886
- https://doi.org/10.1080/00958970802187134
Abstract
An X-ray structure of a Co(II) complex of bidentate chelating 2-acetyl-1,3-indandione (2AID) is reported–Co(2AID)2(H2O)2 · 2H2O. The compound crystallizes in the monoclinic space group P21/n with four molecules per unit cell. The molecular structure shows distorted octahedral geometry of the metal center. The complex is characterized by EPR and magnetic measurements, which show high-spin electronic structure for the metal ion.Keywords
This publication has 8 references indexed in Scilit:
- Spectral-structural correlations in high-spin cobalt(II) complexesPublished by Springer Science and Business Media LLC ,2007
- X-ray and 57Fe Mössbauer study on a Fe(III) complex of 2-acetyl-1,3-indandioneInorganica Chimica Acta, 2006
- Synthesis and Structural Studies of Two New Base Adducts of Bis(2,4‐pentanedionato)cobalt(II)European Journal of Inorganic Chemistry, 2004
- Antioxidative activity and active site of 1,3-indandiones with the β-diketone moietyPolymer Degradation and Stability, 2002
- Quantum chemical and spectroscopic study of the structure of 2-acetylindan-1,3-dione complexes with metal(II) ionsJournal of Molecular Structure, 2001
- ESR spectra of low-symmetry high-spin cobalt(II) complexes. 6. 6-Methylquinoline, pyridine, and water adducts of cobalt(II) acetylacetonateInorganic Chemistry, 1980
- The structure of two 2-acyl-1,3-indandionesActa Crystallographica Section B: Structural Science, Crystal Engineering and Materials, 1980
- A spectrophotometric study of ferric and uranyl chelates of some 2-acylindane-1,3-dionesCollection of Czechoslovak Chemical Communications, 1970