Synthesis and Photoluminescence Properties of Divalent Europium Doped-CaAlSi1+2xN3+2xOx(x= 0–1) Solid Solution Phosphors
- 22 May 2013
- journal article
- Published by The Electrochemical Society in ECS Journal of Solid State Science and Technology
- Vol. 2 (7), R131-R134
- https://doi.org/10.1149/2.014307jss
Abstract
The calcium cyanamide (CaCN2) reduction route was applied for the synthesis of the Eu2+ (2 at%)-activated CaAlSi1+2xN3+2xOx (x = 0–1) phosphors, and the impact of oxygen content on photoluminescence properties was investigated. The relationship of crystallographic parameters of the solid solution and oxygen content were also studied. All of the samples showed a broadband excitation covering the range from UV to visible region, revealing that this phosphor was a potential candidate for the phosphor-converted white LEDs. Under the UV/blue excitation, this series phosphor gave the emission peaks varying from 585 to 641 nm. The shifting behavior was dominantly contributed to the second luminescent center formed by the introduction of oxygen into nitride phosphors.Keywords
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