Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition of Allene-dienes
- 4 December 2009
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 12 (1), 200-203
- https://doi.org/10.1021/ol902622b
Abstract
An enantioselective gold(I)-catalyzed intramolecular [4 + 2]-cycloaddition of allenes and dienes is reported. The reactions allow for the asymmetric synthesis of trans-hexahydroindenes and pyrrolidine products using C3-symmetric phosphitegold(I) and ortho-arylphosphoramiditegold(I) complexes as catalysts, respectively.This publication has 41 references indexed in Scilit:
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