Ruthenium(II) carbonyl complexes with N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives and triphenylphosphine as effective catalysts for oxidation of alcohols
- 10 January 2011
- journal article
- research article
- Published by Taylor & Francis Ltd in Journal of Coordination Chemistry
- Vol. 64 (3), 491-501
- https://doi.org/10.1080/00958972.2010.548007
Abstract
Ruthenium(II) complexes, [RuCl(L)(CO)(PPh3)2] {where L = N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives}, are prepared from reaction between [RuHCl(CO)(PPh3)3] and N-[di(alkyl/aryl)carbamothioyl]benzamide derivatives in toluene and characterized by elemental analysis and spectral data (electronic, infrared, 1H NMR, and 31P NMR). The combination of [RuCl(L)(CO)(PPh3)2] (0.01 mmol) and N-methylmorpholine-N-oxide (NMO) (3 mmol) is an active catalyst for the oxidation of primary, secondary, cyclic, allylic, aliphatic, and benzylic alcohols to their corresponding aldehydes and ketones at room temperature. The oxidation protocol is simple to operate and gives the corresponding carbonyl compounds good to excellent yields.Keywords
This publication has 38 references indexed in Scilit:
- Cationic palladium(II), platinum(II) and ruthenium(II) complexes containing a chelating difluoro-substituted thiourea ligandPolyhedron, 2010
- Strategies for oxidation catalyzed by polyoxometalates at the interface of homogeneous and heterogeneous catalysisTopics in Catalysis, 2005
- Transition Metals for Organic SynthesisPublished by Wiley ,2004
- Green, Catalytic Oxidation of Alcohols in WaterScience, 2000
- Chiral and achiral platinum(II) complexes for potential use as chemotherapeutic agents: crystal and molecular structures of cis-[Pt(L1)2] and [Pt(L1)Cl(MPSO)] [HL1 = N,N-diethyl-N ′-benzoylthiourea]J. Chem. Soc., Dalton Trans., 2000
- Self-association of new mixed-ligand diimine–N-acyl-N′,N′-dialkyl thioureate complexes of platinum(II) in acetonitrile solution †J. Chem. Soc., Dalton Trans., 1998
- Rhenium(V) Oxo Complexes of Novel N2S2 Dithiourea (DTU) Chelate Ligands: Synthesis and Structural CharacterizationInorganic Chemistry, 1996
- Generation of Cp2Mo:S and cycloaddition of the molybdenum sulfido bond with di-p-tolylcarbodiimideInorganic Chemistry, 1993
- Thiadiazatrimethylenemethane and N,N′,P-triphenylphosphonothioic diamide complexes of platinum(II)J. Chem. Soc., Dalton Trans., 1992
- Synthesis and structure of bis(1,1-diethyl-3-(2-chlorobenzoyl)thioureido)nickel(II)Inorganica Chimica Acta, 1988