Reaction-Driven Surface Restructuring and Selectivity Control in Allylic Alcohol Catalytic Aerobic Oxidation over Pd
- 25 March 2011
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 133 (15), 5724-5727
- https://doi.org/10.1021/ja200684f
Abstract
Synchronous, time-resolved DRIFTS/MS/XAS cycling studies of the vapor-phase selective aerobic oxidation of crotyl alcohol over nanoparticulate Pd have revealed surface oxide as the desired catalytically active phase, with dynamic, reaction-induced Pd redox processes controlling selective versus combustion pathways.This publication has 24 references indexed in Scilit:
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