A polymeric-semiconductor–metal-complex hybrid photocatalyst for visible-light CO2 reduction
- 28 August 2013
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 49 (86), 10127-10129
- https://doi.org/10.1039/c3cc45532g
Abstract
A polymeric carbon nitride semiconductor is demonstrated to photocatalyse CO2 reduction to formic acid under visible light (λ > 400 nm) with a high turnover number (>200 for 20 hours) and selectivity (>80%), when coupled with a molecular ruthenium complex as a catalyst.Keywords
This publication has 22 references indexed in Scilit:
- Photocatalytic CO 2 reduction with high turnover frequency and selectivity of formic acid formation using Ru(II) multinuclear complexesProceedings of the National Academy of Sciences, 2012
- Photocatalytic Reduction of Carbon Dioxide over Ag Cocatalyst-Loaded ALa4Ti4O15 (A = Ca, Sr, and Ba) Using Water as a Reducing ReagentJournal of the American Chemical Society, 2011
- Photochemical Reduction of CO2 Using TiO2: Effects of Organic Adsorbates on TiO2 and Deposition of Pd onto TiO2ACS Applied Materials & Interfaces, 2011
- Development of efficient photocatalytic systems for CO2 reduction using mononuclear and multinuclear metal complexes based on mechanistic studiesCoordination Chemistry Reviews, 2010
- Molecular Approaches to the Photocatalytic Reduction of Carbon Dioxide for Solar FuelsAccounts of Chemical Research, 2009
- Development of an Efficient Photocatalytic System for CO2 Reduction Using Rhenium(I) Complexes Based on Mechanistic StudiesJournal of the American Chemical Society, 2008
- Photoreduction of Carbon Dioxide with Methane over ZrO2Chemistry Letters, 1997
- Artificial Photosynthesis: Solar Splitting of Water to Hydrogen and OxygenAccounts of Chemical Research, 1995
- Electrochemical CO2 reduction catalyzed by ruthenium complexes [Ru(bpy)2(CO)2]2+ and [Ru(bpy)2(CO)Cl]+. Effect of pH on the formation of CO and HCOO-Organometallics, 1987
- Efficient photochemical reduction of CO2to CO by visible light irradiation of systems containing Re(bipy)(CO)3X or Ru(bipy)32+–Co2+combinations as homogeneous catalystsJournal of the Chemical Society, Chemical Communications, 1983