Recent developments in transition metal diaryl chemistry
- 9 December 2010
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Dalton Transactions
- Vol. 40 (4), 769-778
- https://doi.org/10.1039/c0dt01247e
Abstract
This Perspective discusses the synthesis and reactivity of low-coordinate transition metal diaryl complexes. The development of sterically demanding ligands, in particular m-terphenyls is facilitating the isolation of complexes featuring two-coordinate open-shell transition metal centres. These coordinatively unsaturated complexes are now being investigated for their reaction chemistry, which is not only contributing to the elucidation of the structure and bonding within these systems but is also leading to the formation of novel compounds.Keywords
This publication has 104 references indexed in Scilit:
- Direct Spectroscopic Observation of Large Quenching of First-Order Orbital Angular Momentum with Bending in Monomeric, Two-Coordinate Fe(II) Primary Amido Complexes and the Profound Magnetic Effects of the Absence of Jahn− and Renner−Teller Distortions in Rigorously Linear CoordinationJournal of the American Chemical Society, 2009
- Morphological and Phase Controlled Tungsten Based Nanoparticles: Synthesis and Characterization of Scheelite, Wolframite, and Oxide NanomaterialsChemistry of Materials, 2008
- Core/Shell Quantum Dots with High Relaxivity and Photoluminescence for Multimodality ImagingJournal of the American Chemical Society, 2007
- Stable, Two-Coordinate, Open Shell (d0—d9) Transition Metal ComplexesComments on Inorganic Chemistry, 1989
- The molecular structure of monomeric base-free bis(neopentyl)manganese by gas electron diffractionJournal of the Chemical Society, Chemical Communications, 1985
- Preparation and crystal structure of a two-co-ordinate manganese compound, bis[tris(trimethyl)silylmethyl]manganeseJournal of the Chemical Society, Chemical Communications, 1985
- A homoleptic arylmanganese(II) complex : synthesis and structure of a thermally stable trinuclear mesitylmanganese(II) complexJournal of the Chemical Society, Chemical Communications, 1983
- Cyclotrimerization of 2-butyne-1,1,1-d3 by transition metal catalystsJournal of the American Chemical Society, 1969
- π-Complexes of the Transition Metals. XIII. Acetylenic Condensations on Nickel(II) and Chromium(II)1Journal of the American Chemical Society, 1960
- π-Complexes of the Transition Metals. VII. The Reaction of Phenylmagnesium Bromide with Chromium Halides1Journal of the American Chemical Society, 1959