Effects of γ-Irradiation on the Free Radical and Antioxidant Contents in Nine Aromatic Herbs and Spices
- 17 December 2002
- journal article
- Published by American Chemical Society (ACS) in Journal of Agricultural and Food Chemistry
- Vol. 51 (4), 927-934
- https://doi.org/10.1021/jf020739n
Abstract
Nine spice and aromatic herb samples (i.e., basil, bird pepper, black pepper, cinnamon, nutmeg, oregano, parsley, rosemary, and sage) were γ-irradiated at a dose of 10 kGy according to commercial practices. The effects of the disinfection treatment on the content of organic radicals and some nutrients (namely, vitamin C and carotenoids) in the samples were investigated by chromatographic and spectroscopic techniques. Irradiation resulted in a general increase of quinone radical content in all of the investigated samples, as revealed by electron paramagnetic resonance spectroscopy. The fate of these radicals after storage for 3 months was also investigated. The cellulose radical was clearly observed in a few samples. Significant losses of total ascorbate were found for black pepper, cinnamon, nutmeg, oregano, and sage, whereas a significant decrease of carotenoids content was observed for cinnamon, oregano, parsley, rosemary, bird pepper, and sage. Keywords: Spices; aromatic herbs; antioxidants; ascorbate; carotenoids; front-surface spectroscopy; γ-ray irradiation; EPR; free radicalsThis publication has 39 references indexed in Scilit:
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