Ion-tagged π-acidic alkene ligands promote Pd-catalysed allyl–aryl couplings in an ionic liquid
- 2 September 2009
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 38,p. 5734-5736
- https://doi.org/10.1039/b906823f
Abstract
Ionic π-acidic alkene ligands based on chalcone and benzylidene acetone frameworks have been “doped” into ionic liquids to provide functional reaction media for Pd-catalysed cross-couplings of a cyclohexenyl carbonate with aryl siloxanes that allow simple product isolation, free from Pd (<50 ppm) and ligand contamination.Keywords
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