Design and Synthesis of 3d−4f Metal-Based Zeolite-type Materials with a 3D Nanotubular Structure Encapsulated “Water” Pipe
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- 20 February 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (10), 3012-3013
- https://doi.org/10.1021/ja038784e
Abstract
A nanotubular 3D heterometallic zeolitic polymer, {[Yb(PDA)3Mn1.5(H2O)3]·1.5H2O}n (2), was designed and synthesized by simply tuning the amount of coordinated water on the Mn ion in the molecular ladder polymer {[Yb(PDA)3Mn1.5(H2O)6]·6H2O}n (1). 1 and 2 were structurally and magnetically characterized. The water molecules capsulated within the nanotube were arrayed into an unprecedented “water” pipe. The robust 2 retained intact networks after the removal of guest water trapped in the nanotubes and even after methanol replaced guest water.Keywords
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