One-pot Synthesis of Permethylated α-CD-based Rotaxanes Having Alkylene Chain Axles and Their Structural Characteristics
- 28 July 2012
- journal article
- research article
- Published by Oxford University Press (OUP) in Chemistry Letters
- Vol. 41 (8), 806-808
- https://doi.org/10.1246/cl.2012.806
Abstract
Permethylated α-CD-based rotaxanes with short alkylene chains as an axle were synthesized through urea end-capping in one pot: Products were [2]rotaxane and [3]rotaxane. The head-to-head structure of [3]rotaxane obtained as a single isomer was confirmed by the characteristic 1H NMR peak shifts and X-ray single-crystal structure analysis.Keywords
This publication has 57 references indexed in Scilit:
- Novel Cross-Linking Concept of Polymer Network: Synthesis, Structure, and Properties of Slide-Ring Gels with Freely Movable JunctionsPolymer Journal, 2007
- Insulated Molecular WiresAngewandte Chemie, 2007
- Polyrotaxane and Polyrotaxane Network: Supramolecular Architectures Based on the Concept of Dynamic Covalent Bond ChemistryPolymer Journal, 2006
- Polyrotaxanes and Polycatenanes: Recent Advances in Syntheses and Applications of Polymers Comprising of Interlocked StructuresPublished by Springer Science and Business Media LLC ,2004
- Cyclodextrin-Based Molecular MachinesAccounts of Chemical Research, 2001
- Cyclodextrin-Based Catenanes and RotaxanesChemical Reviews, 1998
- PolyrotaxanesActa Polymerica, 1998
- Rotaxanes, catenanes, polyrotaxanes, polycatenanes and related materialsProgress in Polymer Science, 1994
- Double-stranded inclusion complexes of cyclodextrin threaded on poly(ethylene glycol)Nature, 1994
- The molecular necklace: a rotaxane containing many threaded α-cyclodextrinsNature, 1992