Basic data of polyatomic ion-molecule systems for flue gas discharge modelling
- 6 November 2001
- journal article
- Published by IOP Publishing in Journal of Physics D: Applied Physics
- Vol. 34 (22), 3247-3255
- https://doi.org/10.1088/0022-3727/34/22/308
Abstract
In the presence of an external electric field, ion transport coefficients (ion mobility and diffusion coefficients) are closely related to the ion-neutral interaction potential. A new generalized potential model, coupled to an optimized Monte Carlo technique, has been developed for the determination of the transport coefficients of polyatomic ions in weakly ionized gases. This corresponds to the polyatomic ion-molecule systems which can affect the electrical behaviour of the flue gas discharges used for the non-thermal plasma reactor for pollution control. The ion-molecule interaction has been described by a rigid core potential model which is adapted for both polar and non-polar systems and also symmetric and asymmetric systems. Momentum transfer cross sections are then determined using a semi-classical approach. The corresponding sets of cross sections including the dominant processes in our intermediate ion energy range (elastic and mainly charge transfer in certain cases) are used in the Monte Carlo code to calculate the ion transport coefficients over a wide range of reduced electric field E/N. These ion transport data fit quite well the drift tube measurements available in the literature for the CO2+/CO2 system, and also for certain weakly polar cases. The case of the H2O+/H2O system is then considered thus giving in this highly polar system the ion swarm data for the first time in the literature. Finally, we have considered with quite good reliability some asymmetric systems such as CO2+/N2 and N2+/CO2 whose ion data are also needed for flue gas discharge modelling.Keywords
This publication has 19 references indexed in Scilit:
- Transport Properties of Gaseous Ions over a Wide Energy Range, IVAtomic Data and Nuclear Data Tables, 1995
- Absolute state-selected and state-to-state total cross sections for the Ar+(2P3/2,1/2)+CO2 reactionsThe Journal of Chemical Physics, 1992
- Reaction cross section and product ion time-of-flight measurements for collisions of N+ and N+2 with CO2 at suprathermal energiesThe Journal of Chemical Physics, 1990
- Transport properties of gaseous ions over a wide energy range. Part IIIAtomic Data and Nuclear Data Tables, 1984
- Transport properties of gaseous ions over a wide energy range. Part IIAtomic Data and Nuclear Data Tables, 1978
- Transport properties of gaseous ions over a wide energy rangeAtomic Data and Nuclear Data Tables, 1976
- Low Energy Ion-Neutral Reactions. V. O2++NO, N2++NO, CO++NO, N2++O2, CO2++O2, CO++O2 and N2++COJournal of the Physics Society Japan, 1974
- Mobilities of polyatomic ions in gases: core modelJournal of Physics B: Atomic and Molecular Physics, 1972
- Some Aspects of the Quantal and Semiclassical Calculation of Phase Shifts and Cross Sections for Molecular Scattering and TransportThe Journal of Chemical Physics, 1964
- Mobility of gaseous lons in weak electric fieldsAnnals of Physics, 1958