Activation of H2O2 by Chiral Confined Brønsted Acids: A Highly Enantioselective Catalytic Sulfoxidation
- 25 June 2012
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 134 (26), 10765-10768
- https://doi.org/10.1021/ja3035637
Abstract
Confined chiral Brønsted acids are shown to catalyze asymmetric oxidations of sulfides to sulfoxides with hydrogen peroxide. The wide generality and high enantioselectivity of the developed method compare even to the best metal-based systems and suggest utility in other asymmetric oxidationsThis publication has 63 references indexed in Scilit:
- Asymmetric Organocatalytic Cyclization and Cycloaddition ReactionsChemical Reviews, 2011
- Catalytic Asymmetric Epoxidation of α-Branched EnalsJournal of the American Chemical Society, 2010
- Catalytic Asymmetric Hydroperoxidation of α,β‐Unsaturated Ketones: An Approach to Enantiopure Peroxyhemiketals, Epoxides, and AldolsAngewandte Chemie, 2008
- Organocatalytic Oxidation. Asymmetric Epoxidation of Olefins Catalyzed by Chiral Ketones and Iminium SaltsChemical Reviews, 2008
- Catalytic Asymmetric Epoxidation of Cyclic EnonesJournal of the American Chemical Society, 2008
- Aspartate-Catalyzed Asymmetric Epoxidation ReactionsJournal of the American Chemical Society, 2007
- Asymmetric Organocatalytic Epoxidation of α,β-Unsaturated Aldehydes with Hydrogen PeroxideJournal of the American Chemical Society, 2005
- Organocatalytic Asymmetric Hydroxylation of β-Keto Esters: Metal-Free Synthesis of Optically Active anti-DiolsThe Journal of Organic Chemistry, 2004
- Modern Oxidation MethodsPublished by Wiley ,2004
- Biomimetic Oxidations Catalyzed by Transition Metal ComplexesPublished by World Scientific Pub Co Pte Ltd ,2000