Highly Stereoselective Synthesis of Trisubstituted Vinylcyclopropane Derivatives via Arsonium Ylides
- 1 November 2005
- journal article
- research article
- Published by American Chemical Society (ACS) in The Journal of Organic Chemistry
- Vol. 70 (24), 10202-10205
- https://doi.org/10.1021/jo051782n
Abstract
Alkylidene or arylidene malonates reacted with arsonium allylides to give trans-disubstituted cyclopropane-1,1-dicarboxylates with high stereoselectivity in high yields. The mechanism of the cyclopropanation reactions has also been investigated.Keywords
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