The first 3-D ferrimagnetic nickel fumarate with an open framework: [Ni3(OH)2(O2C–C2H2–CO2)(H2O)4]·2H2O

Abstract
A three-dimensional nickel fumarate has been isolated by hydrothermal reaction and its structure solved from powder X-ray diffraction; its organisation reveals an unusual topology not previously seen in nickel chemistry and provided a scarce ferrimagnetic behaviour below 20 K.

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