Direct observation of ion evaporation from a triply charged nanodroplet
- 24 September 2007
- journal article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- No. 40,p. 4099-4101
- https://doi.org/10.1039/b711689f
Abstract
Triply charged, highly solvated metal ions of the form [Ln(H2O)n]3+ can be generated using a commercial mass spectrometer, and CID studies on these highly charged metal–solvent clusters allow for the direct observation of a process best described as ion evaporation.Keywords
This publication has 29 references indexed in Scilit:
- Coordination of Triply Charged Lanthanum in the Gas Phase: Theory and ExperimentChemistry – A European Journal, 2007
- On the distributions of ion/neutral molecule clusters in electrospray and laser spray—A cluster division model for the electrospray processJournal of the American Society for Mass Spectrometry, 2006
- What Is Required to Stabilize Al3+? A Gas-Phase PerspectiveJournal of the American Chemical Society, 2005
- Metal Ion Solvation in the Gas Phase: The Quest for Higher Oxidation StatesThe Journal of Physical Chemistry A, 2002
- Observation of triply charged metal ion clusters by electrospray and laser sprayRapid Communications in Mass Spectrometry, 1999
- Cluster ion studies of Ho2+ and Ho3+ solvation in the gas phaseInternational Journal of Mass Spectrometry, 1999
- Unimolecular Reactions of Dihydrated Alkaline Earth Metal Dications M2+(H2O)2, M = Be, Mg, Ca, Sr, and Ba: Salt-Bridge Mechanism in the Proton-Transfer Reaction M2+(H2O)2 → MOH+ + H3O+Journal of the American Chemical Society, 1999
- Water cluster calibration reduces mass error in electrospray ionization mass spectrometry of proteinsJournal of the American Society for Mass Spectrometry, 1997
- Solvent‐derived metal oxides in electrospray mass spectrometry of metal salt solutionsJournal of Mass Spectrometry, 1992
- First studies of the gas phase ion chemistry of M3+ metal ion ligandsInternational Journal of Mass Spectrometry and Ion Processes, 1990