Chemistry of a geminal frustrated Lewis pair featuring electron withdrawing C6F5 substituents at both phosphorus and boron
- 1 March 2011
- journal article
- research article
- Published by Royal Society of Chemistry (RSC) in Chemical Communications
- Vol. 47 (14), 4288-4290
- https://doi.org/10.1039/c1cc10241a
Abstract
Hydroboration of the electron poor phosphine (1-propenyl)P(C6F5)2 with Piers' borane [HB(C6F5)2 ] gave the geminal frustrated Lewis pair (C6F5)2P–CH(Et)–B(C6F5)2 . It undergoes 1,2-addition reactions to an alkene and an alkyne and to the CN bond of an isocyanate. With mesityl azide it undergoes a 1,3-addition reaction.Keywords
This publication has 29 references indexed in Scilit:
- Structure and Dynamic Features of an Intramolecular Frustrated Lewis PairChemistry – A European Journal, 2010
- Addition reactions to the intramolecular mesityl2P–CH2–CH2–B(C6F5)2 frustrated Lewis pairDalton Transactions, 2010
- Frustrierte Lewis‐Paare: metallfreie Wasserstoffaktivierung und mehrAngewandte Chemie, 2009
- Metal-free dihydrogen activation chemistry: structural and dynamic features of intramolecular P/B pairsDalton Transactions, 2009
- Metallfreie katalytische Hydrierung von Enaminen, Iminen und konjugierten PhosphinoalkenylboranenAngewandte Chemie, 2008
- Rapid intramolecular heterolytic dihydrogen activation by a four-membered heterocyclic phosphane–borane adductChemical Communications, 2007
- Facile Heterolytic Cleavage of Dihydrogen by Phosphines and BoranesJournal of the American Chemical Society, 2007
- Struktur und Reaktionsweise organischer at‐KomplexeAngewandte Chemie, 1966
- Über das Verhalten von Dehydrobenzol gegenüber nucleophilen und elektrophilen ReagenzienEuropean Journal of Inorganic Chemistry, 1959
- Studies in Stereochemistry. I. Steric Strains as a Factor in the Relative Stability of Some Coördination Compounds of BoronJournal of the American Chemical Society, 1942