Electronic structures and low-dimensional magnetic properties of the ordered rocksalt oxides and
- 5 September 2007
- journal article
- research article
- Published by American Physical Society (APS) in Physical Review B
- Vol. 76 (10), 104403
- https://doi.org/10.1103/physrevb.76.104403
Abstract
The ordered rocksalt-type oxide was synthesized and its magnetic properties were investigated. The broad peak in the temperature-dependent magnetic susceptibility data near is indicative of the dominant low-dimensional short-range antiferromagnetic (AF) behavior. The data are very well fitted with the AF-AF alternating linear chain model with and . The high-temperature data exhibit Curie-Weiss behavior with a Weiss temperature of . These results are very similar to those reported for the isostructural oxide [J. Xu et al., Inorg. Chem. 44, 5042 (2005)]. Recently, it was shown [Y. Miura et al., J. Phys. Soc. Jpn. 75, 847071 (2006)] that an AF-ferromagnetic (F) linear chain model gives an equally good fit to the low-temperature data for both compounds and that further analysis of magnetic heat capacity data supports the AF-F model. We reinvestigate this proposal by computing the intersite hopping integrals using both the tight-binding spin dimer analysis and the -order muffin-tin-orbital downfolding procedure for both compounds. The calculations support the AF-AF model for the antimonide. Further, the Weiss temperatures derived from the high-temperature experimental data, , are also consistent with the values derived from the AF-AF model but not with those obtained from the AF-F alternative.
Keywords
This publication has 10 references indexed in Scilit:
- Synthesis, Structure, and Magnetic Properties of the Layered Copper(II) Oxide Na2Cu2TeO6Inorganic Chemistry, 2005
- Subsolidus phase relations in Na2O–CuO–Sb2On system and crystal structure of new sodium copper antimonate Na3Cu2SbO6Journal of Solid State Chemistry, 2005
- Spin exchange interactions and magnetic structures of extended magnetic solids with localized spins: theoretical descriptions on formal, quantitative and qualitative levelsJournal of Solid State Chemistry, 2003
- Muffin-tin orbitals of arbitrary orderPhysical Review B, 2000
- Li4MgReO6: An S=1/2 antiferromagnet exhibiting spin-glass behaviorPhysical Review B, 2000
- Two-Dimensional Short-Range Magnetic Order in the Tetragonal Spinel Li2Mn2O4Chemistry of Materials, 1999
- Long Range and Short Range Magnetic Order in Orthorhombic LiMnO2Journal of Solid State Chemistry, 1997
- Explicit, First-Principles Tight-Binding TheoryPhysical Review Letters, 1984
- Exchange coupling in the alternating-chain compounds catena-di-.mu.-chloro-bis(4-methylpyridine)copper(II), catena-di-.mu.-bromobis(N-methylimidazole)copper(II), catena-[hexanedione)bis(thiosemicarbazonato)]copper(II), and catena-[octanedione bis (thiosemicarbazonato)]copper(II)Inorganic Chemistry, 1981
- Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenidesActa Crystallographica Section A, 1976