Mesostructured Selenides with Cubic MCM-48 Type Symmetry: Large Framework Elasticity and Uncommon Resiliency to Strong Acids
- 5 November 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 126 (47), 15326-15327
- https://doi.org/10.1021/ja044954r
Abstract
The metal mesostructured Pt/Sn/Se chalcogenides with cubic MCM-48 type pore symmetry are found to be surprisingly stable in concentrated oxidizing acids. Their metal chalcogenide framework exhibits high flexibility during reversible proton exchange as it expands and contracts in an apparent breathing-like action.This publication has 8 references indexed in Scilit:
- Endo‐ and Exotemplating to Create High‐Surface‐Area Inorganic MaterialsAngewandte Chemie, 2003
- Synthesis of Periodic Hexagonal Surfactant Templated Platinum Tin Tellurides: Narrow Band Gap Inorganic/Organic CompositesJournal of the American Chemical Society, 2003
- Single-Crystal Mesostructured Semiconductors with Cubic Ia3̄d Symmetry and Ion-Exchange PropertiesJournal of the American Chemical Society, 2002
- Varied pore organization in mesostructured semiconductors based on the [SnSe4]4- anionNature, 2001
- Non-aqueous supramolecular assembly of mesostructured metal germanium sulphides from (Ge4S10)4− clustersNature, 1999
- Influence of Template Extraction on Structure, Activity, and Stability of MCM-41 CatalystsJournal of Catalysis, 1997
- Structure of MCM-48 Revealed by Transmission Electron MicroscopyChemistry of Materials, 1996
- Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanismNature, 1992