An Exceptional 54-Fold Interpenetrated Coordination Polymer with 103-srs Network Topology
- 5 July 2011
- journal article
- research article
- Published by American Chemical Society (ACS) in Journal of the American Chemical Society
- Vol. 133 (30), 11406-11409
- https://doi.org/10.1021/ja202303b
Abstract
Entanglement is one of the most important features of coordination polymer frameworks and has attracted considerable attention due to its aesthetic and topological interest. Among entangled systems, interpenetrating frameworks represent an intriguing subset; however, there are few examples of materials containing very high levels of interpenetration. In this work a coordination polymer with 103-srs topology, constructed from a star-like tridentate ligand, tri(4-imidazolylphenyl)amine, and AgI ions, has been hydrothermally synthesized. It contains a record 54 interpenetrating networks.Keywords
This publication has 21 references indexed in Scilit:
- An unprecedented 2D → 3D metal–organic polyrotaxane framework constructed from cadmium and a flexible star-like ligandChemical Communications, 2010
- Selective sorption of oxygen and nitric oxide by an electron-donating flexible porous coordination polymerNature Chemistry, 2010
- Vertex-, face-, point-, Schläfli-, and Delaney-symbols in nets, polyhedra and tilings: recommended terminologyCrystEngComm, 2009
- Colossal cages in zeolitic imidazolate frameworks as selective carbon dioxide reservoirsNature, 2008
- Unusual parallel and inclined interlocking modes in polyrotaxane-like metal–organic frameworksChemical Communications, 2008
- Metal–organic frameworks incorporating Cu3(μ3-OH) clustersDalton Transactions, 2006
- A chiral, heterometallic metal-organic framework derived from a tris(chelate) coordination complexChemical Communications, 2005
- Interpenetrating metal–organic and inorganic 3D networks: a computer-aided systematic investigation. Part I. Analysis of the Cambridge structural databaseCrystEngComm, 2004
- Functional Porous Coordination PolymersAngewandte Chemie-International Edition, 2004
- Metal Carboxylates with Open ArchitecturesAngewandte Chemie-International Edition, 2004