Gaseous Heterogeneous Catalytic Reactions over Mn-Based Oxides for Environmental Applications: A Critical Review
Top Cited Papers
- 17 July 2017
- journal article
- review article
- Published by American Chemical Society (ACS) in Environmental Science & Technology
- Vol. 51 (16), 8879-8892
- https://doi.org/10.1021/acs.est.6b06079
Abstract
Manganese oxide has been recognized as one of the most promising gaseous heterogeneous catalyst due to its low cost, environmental friendliness and high catalytic oxidation performance. Mn-based oxides can be classified into four types: 1) single manganese oxide (MnOx), 2) supported manganese oxide (MnOx/Support), 3) composite manganese oxides (MnOx-X), and 4) special crystalline manganese oxides (S-MnOx). These Mn-based oxides have been widely used as catalysts for the elimination of gaseous pollutants. This review aims to describe the environmental applications of these manganese oxides and provide perspectives. It gives detailed descriptions of environmental applications of the selective catalytic reduction of NOx with NH3, the catalytic combustion of VOCs, Hg0 oxidation and adsorption, and soot oxidation, in addition to some other environmental applications. Furthermore, this review mainly focuses on the effects of structure, morphology, and modified elements and on the role of catalyst supports in gaseous heterogeneous catalytic reactions. Finally, future research directions for developing manganese oxide catalysts are proposed.Keywords
Funding Information
- Ministry of Science and Technology of the People's Republic of China (2013CB430005)
- National Natural Science Foundation of China (51278294, 51478261)
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