H2, N2, CO, and CO2 Sorption Properties of a Series of Robust Sodalite-Type Microporous Coordination Polymers
- 24 February 2006
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 45 (6), 2397-2399
- https://doi.org/10.1021/ic060049r
Abstract
H2, N2, CO, and CO2 are readily incorporated in the porous, 3D sodalitic frameworks of coordination polymers of the [ML2]n type, with M = PdII or CuII and HL = 2-hydroxypyrimidine or 4-hydroxypyrimidine. The metal ion and ligand functionalization modulate their sorption properties, making these materials suitable for gas storage and separation purposes.Keywords
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